Salophen and salen oxo vanadium complexes as catalysts of sulfides oxidation with H2O2: Mechanistic insights
نویسندگان
چکیده
منابع مشابه
Oxidation of organic sulfides by vanadium haloperoxidase model complexes.
In addition to halide oxidation, the vanadium haloperoxidases are capable of oxidizing sulfides to sulfoxides. Four vanadium complexes with tripodal amine ligands, K[VO(O(2))(heida)] (1), VO(2)(bpg) (2), K[VO(2)(ada)] (3), and K(2)[VO(O(2))(nta)] (4), previously shown to perform bromide oxidation (Colpas, G. J.; Hamstra, B. J.; Kampf, J. W.; Pecoraro, V. L. J. Am. Chem. Soc. 1996, 118, 3469-347...
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ژورنال
عنوان ژورنال: Catalysis Today
سال: 2012
ISSN: 0920-5861
DOI: 10.1016/j.cattod.2012.03.032